Chemistry S and P - Block Elements (S - Block Elements Not In Syllabus ) Physical and Chemical Properties of Group 16th Elements Single Correct MCQ
Published on: August 13, 2026

Bond angle in is higher than the bond angle of ( ). The difference is due to

A
Difference in size of S and O
B
Difference in electronegativity of S and O
C
Difference in oxidations states of S and O
D
Difference in shapes of hybrid orbitals of S and O.

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The correct answer is:
B

The difference in the bond angles is linked with the electronegativities of oxygen and sulphur atoms. As

we move down the group from O to Te, the size of central atoms goes on increasing and its electronegativity goes one decreasing. As a result, the position of the two bond pairs shifts away and away from the central atom as we move from to Consequently the repulsion between the bond pairs decreases as we move from to Te and therefore the bond angle decreases in the order :

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